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独立后第20篇 -ZnBr2推进的苯乙炔的碳苷形成反应 Org.Chem.Front.

文章来源:  |  发布时间:2018-06-19  |  作者:  |  浏览次数:  |  【打印】 【关闭

 

ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes

 

 Org. Chem. Front., 2018,5, 1962-1966

 

Ab stra ct


A convenient, mild and high stereoselective C-glycosylation reaction has been developed. Glycosyl acetates were coupled with terminal alkynes via ZnBr2-activation at room temperature. Their applications were further demonstrated by the straightforward synthesis of a key intermediate in the formal synthesis of (+)-varitriol.

 

 

http://pubs.rsc.org/en/content/articlelanding/2018/qo/c8qo00380g#!divAbstract

 

 

 


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